<> "The repository administrator has not yet configured an RDF license."^^ . <> . . . "Induced Conformational Preferences in a Non-chiral β-Ala Residue: X-ray Diffraction, 1H NMR, FT-IR and CD Studies of Boc-β-Ala-D-Ala-NHCH3 and Boc-β-Ala-L-Ala-NHCH3"^^ . "In order to demonstrate the conformational features that can be induced by achiralresidue in a β-Ala moiety, X-raydiffraction structure of Boc-β-Ala-D-Ala-NHCH31 have been determined and compared with Boc-β-Ala-L-Ala-NHCH32. An analysis of the crystal molecular conformations reveals the establishment of non-superimposable stereogeometrical features across β-Ala residues. The supramolecular assembly of the highly ordered L-shaped molecules, generated by the parallel arrangements of the peptide molecules, is stabilised by a network of intermolecular H-bonds between the CO and NH groups. The chiroptical investigations in solvents of varying polarities provide experimental evidence which strongly supports that the stereochemical preferences of the β-Alaresidue can restrict significant conformational averaging"^^ . "1999" . . . "55" . "48" . . "Elsevier Science"^^ . . . "Tetrahedron"^^ . . . "00404020" . . . . . . . . . . . . . "D."^^ . "Velmurgan"^^ . "D. Velmurgan"^^ . . "Baumathi S"^^ . "Ashish"^^ . "Baumathi S Ashish"^^ . . "Raghuvansh"^^ . "Kishore"^^ . "Raghuvansh Kishore"^^ . . . . . . "Induced Conformational Preferences in a Non-chiral β-Ala Residue: X-ray Diffraction, 1H NMR, FT-IR and CD Studies of Boc-β-Ala-D-Ala-NHCH3 and Boc-β-Ala-L-Ala-NHCH3 (PDF)"^^ . . . . . "Induced Conformational Preferences in a Non-chiral β-Ala Residue: X-ray Diffraction, 1H NMR, FT-IR and CD Studies of Boc-β-Ala-D-Ala-NHCH3 and Boc-β-Ala-L-Ala-NHCH3 (Image (PNG))"^^ . . . . . . "Induced Conformational Preferences in a Non-chiral β-Ala Residue: X-ray Diffraction, 1H NMR, FT-IR and CD Studies of Boc-β-Ala-D-Ala-NHCH3 and Boc-β-Ala-L-Ala-NHCH3 (Image (PNG))"^^ . . . . . . "Induced Conformational Preferences in a Non-chiral β-Ala Residue: X-ray Diffraction, 1H NMR, FT-IR and CD Studies of Boc-β-Ala-D-Ala-NHCH3 and Boc-β-Ala-L-Ala-NHCH3 (Image (PNG))"^^ . . . . . . "Induced Conformational Preferences in a Non-chiral β-Ala Residue: X-ray Diffraction, 1H NMR, FT-IR and CD Studies of Boc-β-Ala-D-Ala-NHCH3 and Boc-β-Ala-L-Ala-NHCH3 (Image (PNG))"^^ . . . . . . "Induced Conformational Preferences in a Non-chiral β-Ala Residue: X-ray Diffraction, 1H NMR, FT-IR and CD Studies of Boc-β-Ala-D-Ala-NHCH3 and Boc-β-Ala-L-Ala-NHCH3 (Indexer Terms)"^^ . . . . . "HTML Summary of #799 \n\nInduced Conformational Preferences in a Non-chiral β-Ala Residue: X-ray Diffraction, 1H NMR, FT-IR and CD Studies of Boc-β-Ala-D-Ala-NHCH3 and Boc-β-Ala-L-Ala-NHCH3\n\n" . "text/html" . . . "QD Chemistry"@en . .